Effective adsorption of malachite green with silica gel supported iron-zinc bimetallic nanoparticles

Yıl 2024, Cilt: 8 Sayı: 3, 510 – 523, 28.07.2024

https://doi.org/10.31127/tuje.1413970

Öz

In the present study, a composite material consisting of silica gel 60 supported iron-zinc bimetallic nanoparticles (Si/Fe-ZnNPs) was prepared and characterized by SEM, EDX, FTIR, and XRD analysis. The adsorbent properties of the synthesized composite material were evaluated with the removal of Malachite Green (MG). According to characterization results, the cubic structures and agglomerated nano-sized spherical particles (≈30 nm) were formed. The FT-IR spectrum confirms the formation of Fe-Zn NPs through the observation of the Fe-O stretches and metal-metal stretching vibrations of (Zn2+ – O2ˉ) adsorption bands. Additionally, the FT-IR revealed the presence of Si-O-Si, Si-O-H stretching, and O-Si-O bending vibrations attributed to silica gel 60. The optimal environmental conditions for adsorption were determined to be a natural pH of 3.3, an adsorption temperature of 50°C, and an adsorbent concentration of 1.0 g/L. An increase in equilibrium uptakes of MG was observed with a linear correlation to initial dye concentrations. Thermodynamic studies indicated that the adsorption process was endothermic, non-spontaneous, and increasing disorder at the solid-solution interface during adsorption with positive ΔH, ΔG, and ΔS values, respectively. The experimental results revealed that the Langmuir isotherm model provided the best fit for the equilibrium data. The maximum monolayer coverage capacity of Si/Fe-ZnNPs was 666.67 mg/g at an optimum temperature of 50°C. Further analysis displayed that the kinetic adsorption data adhere to the pseudo-second-order kinetic model. Additionally, Weber-Morris model results revealed the effectiveness of both the film and intra-particle diffusion in the adsorption.

Anahtar Kelimeler

Adsorption, Malachite green, Bimetallic nanoparticles, Silica gel, Composite material

Proje Numarası

Kaynakça

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Yıl 2024, Cilt: 8 Sayı: 3, 510 – 523, 28.07.2024

https://doi.org/10.31127/tuje.1413970

Öz

Proje Numarası

Kaynakça

  • Rathi, B. S., & Kumar, P. S. (2021). Application of adsorption process for effective removal of emerging contaminants from water and wastewater. Environmental pollution (Barking, Essex: 1987), 280, 116995. https://doi.org/10.1016/j.envpol.2021.116995
  • Ahmad, H. R., Aziz, T., Zia-ur-Rehman, M., Sabir, M., & Khalid, H. (2016). Sources and composition of waste water: Threats to plants and soil health. In Soil Science: Agricultural and Environmental Prospectives (349–370). Springer International Publishing. https://doi.org/10.1007/978-3-319-34451-5_16
  • Senthil Kumar, P., Joshiba, G. J., Femina, C. C., Varshini, P., Priyadharshini, S., Arun Karthick, M. S., & Jothirani, R. (2019). A critical review on recent developments in the low-cost adsorption of dyes from wastewater. Desalination And Water Treatment, 172, 395–416. https://doi.org/10.5004/dwt.2019.24613
  • Ahmouda, K., Boudiaf, M., & Benhaoua, B. (2022). A novel study on the preferential attachment of chromophore and auxochrome groups in azo dye adsorption on different greenly synthesized magnetite nanoparticles: investigation of the influence of the mediating plant extract’s acidity. Nanoscale Advances, 4(15),3250–3271. https://doi.org/10.1039/d2na00302c
  • Oruç, Z., Ergüt, M., Uzunoğlu, D., & Özer, A. (2019). Green synthesis of biomass-derived activated carbon/Fe-Zn bimetallic nanoparticles from lemon (Citrus limon (L.) Burm. f.) wastes for heterogeneous Fenton-like decolorization of Reactive Red 2. Journal of Environmental Chemical Engineering, 7(4), 103231. https://doi.org/10.1016/j.jece.2019.103231
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  • Kragović, M., Stojmenović, M., Petrović, J., Loredo, J., Pašalić, S., Nedeljković, A., & Ristović, I. (2019). Influence of Alginate Encapsulation on Point of Zero Charge (pHpzc) and Thermodynamic Properties of the Natural and Fe(III) – Modified Zeolite. Procedia Manufacturing, 32, 286–293. https://doi.org/10.1016/j.promfg.2019.02.216
  • Banerjee, S., & Chattopadhyaya, M. C. (2017). Adsorption characteristics for the removal of a toxic dye, tartrazine from aqueous solutions by a low cost agricultural by-product. Arabian Journal of Chemistry, 10, S1629–S1638. https://doi.org/10.1016/j.arabjc.2013.06.005
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  • Eltaweil, A. S., Ali Mohamed, H., Abd El-Monaem, E. M., & El-Subruiti, G. M. (2020). Mesoporous magnetic biochar composite for enhanced adsorption of malachite green dye: Characterization, adsorption kinetics, thermodynamics and isotherms. Advanced Powder Technology, 31(3), 1253–1263. https://doi.org/10.1016/j.apt.2020.01.005
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  • Hojjati-Najafabadi, A., Nasr Esfahani, P., Davar, F., Aminabhavi, T. M., & Vasseghian, Y. (2023). Adsorptive removal of malachite green using novel GO@ZnO-NiFe2O4-αAl2O3 nanocomposites. Chemical Engineering Journal, 471(May), 144485. https://doi.org/10.1016/j.cej.2023.144485
  • Hashem, A. A., Mahmoud, S. A., Geioushy, R. A., & Fouad, O. A. (2023). Adsorption of malachite green dye over synthesized calcium silicate nanopowders from waste materials. Materials Science and Engineering: B, 295(December 2022), 116605. https://doi.org/10.1016/j.mseb.2023.116605
  • Rajabi, M., Mirza, B., Mahanpoor, K., Mirjalili, M., Najafi, F., Moradi, O., Sadegh, H., Shahryari-ghoshekandi, H. R., Asif, M., Tyagi, I., Agarwal, S., Gupta, V. K. (2016). Adsorption of malachite green from aqueous solution by carboxylate group functionalized multi-walled carbon nanotubes: Determination of equilibrium and kinetics parameters. Journal of Industrial and Engineering Chemistry, 34, 130–138. https://doi.org/10.1016/j.jiec.2015.11.001
  • Haounati, R., Ouachtak, H., El Haouti, R., Akhouairi, S., Largo, F., Akbal, F., Benlhachemi, A., Jada, A., Addi, A. A. (2021). Elaboration and properties of a new SDS/CTAB@Montmorillonite organoclay composite as a superb adsorbent for the removal of malachite green from aqueous solutions. Separation and Purification Technology, 255(2020), 117335. https://doi.org/10.1016/j.seppur.2020.117335
  • Li, X. Y., Wang, W. R., Xue, R. C., Chen, P. Y., Wang, Y., & Yu, L. P. (2023). Carbon dots/silica nanoaggregates for highly efficient adsorption of alizarin red S and malachite green dyes. New Journal of Chemistry, 47(18), 8965–8973. https://doi.org/10.1039/d3nj01273e
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  • Vergis, B. R., Hari Krishna, R., Kottam, N., Nagabhushana, B. M., Sharath, R., & Darukaprasad, B. (2018). Removal of malachite green from aqueous solution by magnetic CuFe2O4 nano-adsorbent synthesized by one pot solution combustion method. Journal of Nanostructure in Chemistry, 8(1), 1–12. https://doi.org/10.1007/s40097-017-0249-y
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  • Sadegh, H., Shahryari-Ghoshekandi, R., Agarwal, S., Tyagi, I., Asif, M., & Gupta, V. K. (2015). Microwave-assisted removal of malachite green by carboxylate functionalized multi-walled carbon nanotubes: Kinetics and equilibrium study. Journal of Molecular Liquids, 206, 151–158. https://doi.org/10.1016/j.molliq.2015.02.007
  • Mohammadi, A., Daemi, H., & Barikani, M. (2014). Fast removal of malachite green dye using novel superparamagnetic sodium alginate-coated Fe3O4 nanoparticles. International Journal of Biological Macromolecules, 69, 447–455. https://doi.org/10.1016/j.ijbiomac.2014.05.042
  • Ali, H., & Ismail, A. M. (2021). Developing montmorillonite/PVDF/PEO microporous membranes for removal of malachite green: adsorption, isotherms, and kinetics. Journal of Polymer Research, 28(11), 429. https://doi.org/10.1007/s10965-021-02789-3
  • Ghaedi, M., Azad, F. N., Dashtian, K., Hajati, S., Goudarzi, A., & Soylak, M. (2016). Central composite design and genetic algorithm applied for the optimization of ultrasonic-assisted removal of malachite green by ZnO Nanorod-loaded activated carbon. Spectrochimica Acta – Part A: Molecular and Biomolecular Spectroscopy, 167, 157–164. https://doi.org/10.1016/j.saa.2016.05.025
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  • Weber, W. J., & Morris, J. C. (1963). Closure to “Kinetics of Adsorption on Carbon from Solution”. Journal of the Sanitary Engineering Division, 89(6), 53–55. https://doi.org/10.1061/jsedai.0000467

Toplam 73 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Çevre Kirliliği ve Önlenmesi
BölümArticles
Yazarlar

Memduha Ergüt SİVAS BİLİM VE TEKNOLOJİ ÜNİVERSİTESİ 0000-0001-7297-1533 Türkiye

Ayla Özer MERSİN ÜNİVERSİTESİ 0000-0002-7824-238X Türkiye

Proje Numarası
Erken Görünüm Tarihi5 Temmuz 2024
Yayımlanma Tarihi28 Temmuz 2024
Gönderilme Tarihi3 Ocak 2024
Kabul Tarihi21 Şubat 2024
Yayımlandığı Sayı Yıl 2024 Cilt: 8 Sayı: 3

Kaynak Göster

APAErgüt, M., & Özer, A. (2024). Effective adsorption of malachite green with silica gel supported iron-zinc bimetallic nanoparticles. Turkish Journal of Engineering, 8(3), 510-523. https://doi.org/10.31127/tuje.1413970
AMAErgüt M, Özer A. Effective adsorption of malachite green with silica gel supported iron-zinc bimetallic nanoparticles. TUJE. Temmuz 2024;8(3):510-523. doi:10.31127/tuje.1413970
ChicagoErgüt, Memduha, ve Ayla Özer. “Effective Adsorption of Malachite Green With Silica Gel Supported Iron-Zinc Bimetallic Nanoparticles”. Turkish Journal of Engineering 8, sy. 3 (Temmuz 2024): 510-23. https://doi.org/10.31127/tuje.1413970.
EndNoteErgüt M, Özer A (01 Temmuz 2024) Effective adsorption of malachite green with silica gel supported iron-zinc bimetallic nanoparticles. Turkish Journal of Engineering 8 3 510–523.
IEEEM. Ergüt ve A. Özer, “Effective adsorption of malachite green with silica gel supported iron-zinc bimetallic nanoparticles”, TUJE, c. 8, sy. 3, ss. 510–523, 2024, doi: 10.31127/tuje.1413970.
ISNADErgüt, Memduha – Özer, Ayla. “Effective Adsorption of Malachite Green With Silica Gel Supported Iron-Zinc Bimetallic Nanoparticles”. Turkish Journal of Engineering 8/3 (Temmuz 2024), 510-523. https://doi.org/10.31127/tuje.1413970.
JAMAErgüt M, Özer A. Effective adsorption of malachite green with silica gel supported iron-zinc bimetallic nanoparticles. TUJE. 2024;8:510–523.
MLAErgüt, Memduha ve Ayla Özer. “Effective Adsorption of Malachite Green With Silica Gel Supported Iron-Zinc Bimetallic Nanoparticles”. Turkish Journal of Engineering, c. 8, sy. 3, 2024, ss. 510-23, doi:10.31127/tuje.1413970.
VancouverErgüt M, Özer A. Effective adsorption of malachite green with silica gel supported iron-zinc bimetallic nanoparticles. TUJE. 2024;8(3):510-23.

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