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Effective Biosorption of Auramin O Dye with Sustainable Chickpea Pods Waste; Isotherms, Kinetics and Thermodynamic Analysis Skip to content Yıl 2024, Cilt: 45 Sayı: 2, 240 – 248, 30.06.2024
Zehra Saba Keskin
https://doi.org/10.17776/csj.1457268
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Radioanal Nucl. Chem., 332 (2023) 2239–2248. [21] Hevira L, Zilfa, Rahmayeni, Ighalo J.O., Zein R., Biosorption of indigo carmine from aqueous solution by Terminalia Catappa shell, J. Environ. Chem. Eng., 8 ( 2020)104290. [22] Akkari I., Graba Z., Bezzi N., Merzeg F.A., Bait N., Ferhati A., Raw pomegranate peel as promise efficient biosorbent for the removal of Basic Red 46 dye: equilibrium, kinetic, and thermodynamic studies, Biomass Convers Biorefinery, 13 ( 2023) 8047–60. [23] Amar I.A., Biosorption Removal of Methylene Blue Dye from Aqueous Solutions using Phosphoric Acid-Treated Balanites Aegyptiaca Seed Husks Powder, Biointerface Research in Applied Chemistry, 12(6) (2022) 7845–62. [24] Al-Asadi S.T., Al-Qaim F.F., Al-Saedi H.F.S., Deyab I.F., Kamyab H., Chelliapan S., Adsorption of methylene blue dye from aqueous solution using low-cost adsorbent: kinetic, isotherm adsorption, and thermodynamic studies, Environ Monit Assess, 195 (2023) 676. [25] Ayawei N., Ebelegi A.N., Wankasi D., Modelling and Interpretation of Adsorption Isotherms, J Chem., 2017 (2017) 3039817. [26] Şenol Z.M., Gül Ü.D., Şimşek S., Bioremoval of Safranin O dye by the identified lichen species called Evernia prunastri biomass; biosorption optimization, isotherms, kinetics, and thermodynamics, Biomass Convers Biorefinery., 12 (2022) 4127–37. [27] Mohammed R.A., Walli H.A., A Study of Removal of Lead (II) Ions from Aqueous Solution on Chitosan-g-poly (acrylic acid-co-crotonic acid) Hydrogel, Int J Drug Deliv Technol., 12 (2022) 1844–8. [28] Keskin Z.S., Şenol Z.M., Kaya S., Şimşek S., Prunus mahaleb shell as a sustainable bioresource for carminic acid removal from aqueous solution: Experimental and theoretical studies, J. Mol. Struct., 1275 (2023) 134618. [29] Al-Ghouti M.A., Da’ana D.A., Guidelines for the use and interpretation of adsorption isotherm models: A review, J. Hazard Mater., 393 (2020) 122383. [30] Dada A.O., Adekola F.A., Odebunmi E.O., Dada F.E., Bello O.M., Akinyemi B.A., et al., Sustainable and low-cost Ocimum gratissimum for biosorption of indigo carmine dye: kinetics, isotherm, and thermodynamic studies, Int. J. Phytoremediation,. 22 (2020) 1524–37. [31] Şenol Z.M., Çetinkaya S., Yenidünya A.F., Başoğlu-Ünal F., Ece A., Epichlorohydrin and tripolyphosphate-crosslinked chitosan–kaolin composite for Auramine O dye removal from aqueous solutions: Experimental study and DFT calculations, Int. J. Biol. Macromol., 199 (2022) 318–30. [32] Sözüdoğru O., Investigation of Effective Removal of Auramine O Dye by Pyracantha Coccinea Biosorbent: Isotherm and Kinetics, Brill Eng.,4 (2023) 1–6. [33] Vaid V., Jindal R., Biodegradable tamarind kernel powder/kappa-carrageenan hydrogel for efficient removal of cationic dyes from effluents, Water Environ. Res., 95 (2023) 1–21. [34] Shakeri S., Rafiee Z., Dashtian K., Fe3O4-Based Melamine-Rich Covalent Organic Polymer for Simultaneous Removal of Auramine O and Rhodamine B., J. Chem. Eng. Data, 65 (2020) 696–705. [35] Duarte E.D.V., Vieira W.T., Góes R.O., de Azevedo L.E.C., Vieira M.G.A., da Silva M.G.C., et al., Amazon raw clay as a precursor of a clay-based adsorbent: experimental study and DFT analysis for the adsorption of Basic Yellow 2 dye, Environ. Sci. Pollut. Res., 30 (2023) 62602–24. A [36] Şenol Z.M., Şimşek S, Equilibrium, kinetics and thermodynamics of Pb(II) ions from aqueous solution by adsorption onto chitosan-dolomite composite beads, Int. J. Environ. Anal. Chem., 102(17) (2022) 4926–40. [37] Thompson C.O., Ndukwe A.O., Asadu C.O., Application of activated biomass waste as an adsorbent for the removal of lead (II) ion from wastewater, Emerg Contam., 6 (2020) 259–67. [38] Şenol Z.M, El Messaoudi N., Fernine Y., Keskin Z.S., Bioremoval of rhodamine B dye from aqueous solution by using agricultural solid waste ( almond shell ): experimental and DFT modeling studies, Biomass Convers Biorefinery, (2023) https://doi.org/10.1007/s13399-023-03781-1. [39] Zafar L., Khan A., Kamran U., Park S., Nawaz H., Eucalyptus ( camaldulensis ) bark-based composites for efficient Basic Blue 41 dye biosorption from aqueous stream : Kinetics , isothermal , and thermodynamic studies, Surfaces and Interfaces , 31 (2022) 101897.
Effective Biosorption of Auramin O Dye with Sustainable Chickpea Pods Waste; Isotherms, Kinetics and Thermodynamic Analysis Yıl 2024, Cilt: 45 Sayı: 2, 240 – 248, 30.06.2024
Zehra Saba Keskin
https://doi.org/10.17776/csj.1457268
Öz This study investigated biosorbent properties in removing Auramin O (AO) dye from the aqueous solution of agricultural wastes released from chickpea (Cicer arietinum L.), which is widely produced in Turkey and the world. Biosorption studies were carried out using different values of parameters such as initial AO concentration, dye pH, contact time, temperature, and biosorbent amount. Characterization analyses of the biosorbent used before and after biosorption were carried out by scanning electron microscopy (SEM), energy dispersive X-ray (EDX), Brunauer–Emmett–Teller (BET), Fourier transform infrared spectroscopy (FTIR), and point of zero charge (PZC). Biosorption isotherms were evaluated using Langmuir, Freundlich, and Dubinin-Radushkevich (D-R) isotherm models. As a result of experimental data, it has been shown that the Langmuir isotherm model (R2 = 0.930) is the most compatible model for biosorption, while the biosorption kinetic mechanism proceeds through the pseudo-second-order (PSO) kinetic model (R2 = 0.965) and the intra-particle diffusion model. As a result of thermodynamic studies, it has been reported that biosorption is endothermic (ΔH0>0), spontaneous (ΔS0>0), and entropy-increasing (ΔG0 <0).
Anahtar Kelimeler Cicer arietinum L. pods, Auramin O, Biosorption
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[16] Petrović M., Šoštarić T., Stojanović M., Milojković J., Mihajlović M., Stanojević M., et al., Removal of Pb2+ ions by raw corn silk (Zea mays L.) as a novel biosorbent, J. Taiwan Inst. Chem. Eng., 58 (2016) 407–16. [17] Fatombi J.K., Lartiges B., Aminou T., Barres O., Caillet C., A natural coagulant protein from copra (Cocos nucifera): Isolation, characterization, and potential for water purification, Sep Purif Technol., 116 (2013) 35–40. [18] Garg U., Kaur M.P., Jawa G.K., Sud D., Garg V.K., Removal of cadmium (II) from aqueous solutions by adsorption on agricultural waste biomass, J. Hazard Mater., 154 (2008) 1149–57. [19] Mansour R.A., El Shahawy A., Attia A., Beheary M.S., Brilliant Green Dye Biosorption Using Activated Carbon Derived from Guava Tree Wood, Int. J. Chem. Eng., 2020 (2020) 8053828. [20] Şenol Z.M., Keskin Z.S., Şimşek S., Synthesis and characterization of a new hybrid polymer composite (pollene@polyacrylamide) and its applicability in uranyl ions adsorption, J. Radioanal Nucl. Chem., 332 (2023) 2239–2248. [21] Hevira L, Zilfa, Rahmayeni, Ighalo J.O., Zein R., Biosorption of indigo carmine from aqueous solution by Terminalia Catappa shell, J. Environ. Chem. Eng., 8 ( 2020)104290. [22] Akkari I., Graba Z., Bezzi N., Merzeg F.A., Bait N., Ferhati A., Raw pomegranate peel as promise efficient biosorbent for the removal of Basic Red 46 dye: equilibrium, kinetic, and thermodynamic studies, Biomass Convers Biorefinery, 13 ( 2023) 8047–60. [23] Amar I.A., Biosorption Removal of Methylene Blue Dye from Aqueous Solutions using Phosphoric Acid-Treated Balanites Aegyptiaca Seed Husks Powder, Biointerface Research in Applied Chemistry, 12(6) (2022) 7845–62. [24] Al-Asadi S.T., Al-Qaim F.F., Al-Saedi H.F.S., Deyab I.F., Kamyab H., Chelliapan S., Adsorption of methylene blue dye from aqueous solution using low-cost adsorbent: kinetic, isotherm adsorption, and thermodynamic studies, Environ Monit Assess, 195 (2023) 676. [25] Ayawei N., Ebelegi A.N., Wankasi D., Modelling and Interpretation of Adsorption Isotherms, J Chem., 2017 (2017) 3039817. [26] Şenol Z.M., Gül Ü.D., Şimşek S., Bioremoval of Safranin O dye by the identified lichen species called Evernia prunastri biomass; biosorption optimization, isotherms, kinetics, and thermodynamics, Biomass Convers Biorefinery., 12 (2022) 4127–37. [27] Mohammed R.A., Walli H.A., A Study of Removal of Lead (II) Ions from Aqueous Solution on Chitosan-g-poly (acrylic acid-co-crotonic acid) Hydrogel, Int J Drug Deliv Technol., 12 (2022) 1844–8. [28] Keskin Z.S., Şenol Z.M., Kaya S., Şimşek S., Prunus mahaleb shell as a sustainable bioresource for carminic acid removal from aqueous solution: Experimental and theoretical studies, J. Mol. Struct., 1275 (2023) 134618. [29] Al-Ghouti M.A., Da’ana D.A., Guidelines for the use and interpretation of adsorption isotherm models: A review, J. Hazard Mater., 393 (2020) 122383. [30] Dada A.O., Adekola F.A., Odebunmi E.O., Dada F.E., Bello O.M., Akinyemi B.A., et al., Sustainable and low-cost Ocimum gratissimum for biosorption of indigo carmine dye: kinetics, isotherm, and thermodynamic studies, Int. J. Phytoremediation,. 22 (2020) 1524–37. [31] Şenol Z.M., Çetinkaya S., Yenidünya A.F., Başoğlu-Ünal F., Ece A., Epichlorohydrin and tripolyphosphate-crosslinked chitosan–kaolin composite for Auramine O dye removal from aqueous solutions: Experimental study and DFT calculations, Int. J. Biol. Macromol., 199 (2022) 318–30. [32] Sözüdoğru O., Investigation of Effective Removal of Auramine O Dye by Pyracantha Coccinea Biosorbent: Isotherm and Kinetics, Brill Eng.,4 (2023) 1–6. [33] Vaid V., Jindal R., Biodegradable tamarind kernel powder/kappa-carrageenan hydrogel for efficient removal of cationic dyes from effluents, Water Environ. Res., 95 (2023) 1–21. [34] Shakeri S., Rafiee Z., Dashtian K., Fe3O4-Based Melamine-Rich Covalent Organic Polymer for Simultaneous Removal of Auramine O and Rhodamine B., J. Chem. Eng. Data, 65 (2020) 696–705. [35] Duarte E.D.V., Vieira W.T., Góes R.O., de Azevedo L.E.C., Vieira M.G.A., da Silva M.G.C., et al., Amazon raw clay as a precursor of a clay-based adsorbent: experimental study and DFT analysis for the adsorption of Basic Yellow 2 dye, Environ. Sci. Pollut. Res., 30 (2023) 62602–24. A [36] Şenol Z.M., Şimşek S, Equilibrium, kinetics and thermodynamics of Pb(II) ions from aqueous solution by adsorption onto chitosan-dolomite composite beads, Int. J. Environ. Anal. Chem., 102(17) (2022) 4926–40. [37] Thompson C.O., Ndukwe A.O., Asadu C.O., Application of activated biomass waste as an adsorbent for the removal of lead (II) ion from wastewater, Emerg Contam., 6 (2020) 259–67. [38] Şenol Z.M, El Messaoudi N., Fernine Y., Keskin Z.S., Bioremoval of rhodamine B dye from aqueous solution by using agricultural solid waste ( almond shell ): experimental and DFT modeling studies, Biomass Convers Biorefinery, (2023) https://doi.org/10.1007/s13399-023-03781-1. [39] Zafar L., Khan A., Kamran U., Park S., Nawaz H., Eucalyptus ( camaldulensis ) bark-based composites for efficient Basic Blue 41 dye biosorption from aqueous stream : Kinetics , isothermal , and thermodynamic studies, Surfaces and Interfaces , 31 (2022) 101897. Toplam 39 adet kaynakça vardır.
Ayrıntılar Birincil Dil İngilizce Konular Çözelti Kimyası Bölüm Natural Sciences Yazarlar Zehra Saba Keskin CUMHURIYET UNIVERSITY, SIVAS VOCATIONAL SCHOOL OF HEALTH SCIENCES 0000-0003-1334-5158 Türkiye
Yayımlanma Tarihi 30 Haziran 2024 Gönderilme Tarihi 22 Mart 2024 Kabul Tarihi 14 Haziran 2024 Yayımlandığı Sayı Yıl 2024Cilt: 45 Sayı: 2
Kaynak Göster APA Keskin, Z. S. (2024). Effective Biosorption of Auramin O Dye with Sustainable Chickpea Pods Waste; Isotherms, Kinetics and Thermodynamic Analysis. Cumhuriyet Science Journal, 45(2), 240-248. https://doi.org/10.17776/csj.1457268
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