REMOVAL OF VETERINARY ANTIBIOTICS BY USING LAYERED DOUBLE HYDROXIDE PHOTOCATALYSTS: EFFECTS OF REACTION PARAMETERS AND KINETIC MODELLING

Yıl 2024, Cilt: 27 Sayı: 3, 804 – 820, 03.09.2024

https://doi.org/10.17780/ksujes.1425244

Öz

The photocatalytic performances of Ni-Fe-LDH, Co-Fe-LDH, and Cu-Fe-LDH, (LDH: Layered Double Hydroxide) were investigated for the removal of oxytetracycline hydrochloride (OTC-HCl) from water. Layered double hydroxide materials were synthesized by using the co-precipitation method. The photocatalysts were characterized by SEM, XRD, XPS, and BET surface area analyses. The highest pharmaceutical removal efficiency was obtained by using Ni-Fe-LDH photocatalyst. Box-Behnken design was used to examine the influences of reaction parameters on OTC-HCl removal and to determine the optimal reaction conditions. In the parametric study, the interactive influences of photocatalyst loading, solution pH, and the initial oxidant concentration on oxytetracycline hydrochloride removal were investigated. Under visible light irradiation, the optimal conditions were determined to be 1.5 g/L catalyst loading, pH 5, and 1.48 mM H2O2 concentration by using Ni-Fe-LDH photocatalyst. OTC-HCl degradation was calculated as 67.1% under the optimal conditions. Hydroxyl radical was determined to be the main effective reactive. Phytotoxicity tests were performed using Lepidium sativum seeds. Veterinary antibiotic degradation fit to first order reaction. The Arrhenius constant and activation energy were evaluated as 2.6 min-1 and 14.21 kJ/mol, respectively.

Anahtar Kelimeler

Layered double hydroxide, Tetracycline antibiotics, Photocatalytic oxidation, Kinetic modelling

Destekleyen Kurum

Ege Üniversitesi

Proje Numarası

FYL-2020-22394

Teşekkür

This study was supported by Ege University Scientific Research Project Fund [FYL-2020-22394].

Kaynakça

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TABAKALI ÇİFT HİDROKSİT FOTOKATALİZÖRLER KULLANARAK VETERİNER ANTİBİYOTİKLERİN GİDERİMİ: REAKSİYON PARAMETRELERİNİN ETKİLERİ VE KİNETİK MODELLEME

Yıl 2024, Cilt: 27 Sayı: 3, 804 – 820, 03.09.2024

https://doi.org/10.17780/ksujes.1425244

Öz

Oksitetrasiklin hidroklorik asidin (OTC-HCl) sudan uzaklaştırılması için Ni-Fe-TÇH, Co-Fe-TÇH ve Cu-Fe-TÇH’nin (TÇH: Tabakalı Çift Hidroksit) fotokatalitik performansları araştırılmıştır. Tabakalı çift hidroksit malzemeler kopresipitasyon yöntemi kullanılarak sentezlenmiştir. Fotokatalizörler SEM, XRD, XPS ve BET yüzey alanı analizleri ile karakterize edilmiştir. En yüksek farmasötik giderim değeri, Ni-Fe-TÇH fotokatalizörünün varlığında elde edilmiştir. Reaksiyon parametrelerinin OTC-HCl giderimi üzerindeki etkilerini araştırmak ve optimum reaksiyon koşullarını belirlemek için Box Behnken tasarımı kullanılmıştır. Parametrik çalışmada fotokatalizör dozu, çözelti pH değeri ve başlangıç oksidan derişiminin oksitetrasiklin hidroklorik asit giderimi üzerine interaktif etkileri incelenmiştir. Ni-Fe-TÇH fotokatalizör kullanılarak görünür ışık altında optimum reaksiyon koşulları 1,5 g/L fotokatalizör dozu, 1,48 mM H2O2 konsantrasyonu ve pH 5 olarak belirlenmiştir. Optimum koşullar altında OTC-HCl giderimi %67,1 olarak hesaplanmıştır. Radikal tuzaklama deneylerinde hidroksil radikalinin başlıca etkili reaktif tür olduğu tespit edilmiştir. Lepidium sativum tohumları kullanılarak fitotoksisite testleri gerçekleştitlmiştir. Kinetik çalışmalarda veteriner antibiyotik bozunmasının birinci dereceden reaksiyon hız modeline uyduğu sonucuna varılmıştır. Aktivasyon enerjisi 14,21 kJ/mol ve ön üstel faktör 2,6 min-1 olarak hesaplanmıştır.

Anahtar Kelimeler

Tabakalı çift hidroksit, Tetrasiklin antibiyotikler, Fotokatalitik oksidasyon, Kinetik modelleme

Destekleyen Kurum

Ege Üniversitesi

Proje Numarası

FYL-2020-22394

Teşekkür

This study was supported by Ege University Scientific Research Project Fund [FYL-2020-22394].

Kaynakça

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Toplam 66 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Atıksu Arıtma Süreçleri
BölümKimya Mühendisliği
Yazarlar

Merve Baraç EGE ÜNİVERSİTESİ 0000-0002-1094-6348 Türkiye

Burcu Palas EGE ÜNİVERSİTESİ 0000-0002-2815-0057 Türkiye

Gülin Ersöz EGE ÜNİVERSİTESİ, MÜHENDİSLİK FAKÜLTESİ 0000-0002-5875-5946 Türkiye

Proje NumarasıFYL-2020-22394
Yayımlanma Tarihi3 Eylül 2024
Gönderilme Tarihi26 Ocak 2024
Kabul Tarihi17 Nisan 2024
Yayımlandığı Sayı Yıl 2024Cilt: 27 Sayı: 3

Kaynak Göster

APABaraç, M., Palas, B., & Ersöz, G. (2024). REMOVAL OF VETERINARY ANTIBIOTICS BY USING LAYERED DOUBLE HYDROXIDE PHOTOCATALYSTS: EFFECTS OF REACTION PARAMETERS AND KINETIC MODELLING. Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi, 27(3), 804-820. https://doi.org/10.17780/ksujes.1425244

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